What is the correct way to say
Merci pour le m'expliquer
Merci pour l'expliquer à moi
If there is a rule that helps me decide, I appreciate it too.
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Neither, the correct sentence is Merci de me l'expliquer.
You use de after merci when it's followed by a verb; pour when it's followed by a noun (merci pour l'explication).
The word order with double pronouns is me + le.